Comparative analysis of volatile fingerprints between different geographical origins and ornamental cultivars of white standard Chrysanthemum (Dendranthema grandiflorum)

Lee, Ji Hye; An, Jae Min; Kim, Yong-Kyoung; Hur, Suel Hye; Park, Sang Un; Kim, Ho Jin

doi:10.1186/s40538-024-00551-7

Chemical and Biological Technologies in Agriculture

Table 1 Concentrations, mean values, and standard deviations of 41 volatile compounds determined in Korean and imported D. grandiflorum

From: Comparative analysis of volatile fingerprints between different geographical origins and ornamental cultivars of white standard Chrysanthemum (Dendranthema grandiflorum)

No	Chemical class	RT (min)	CAS	Formula	Compound name	Korean (%)	Non-Korean (%)
1	Alcohol	8.45	513-86-0	C₄H₈O₂	Acetoin	11.9 ± 6.4	14.4 ± 3.8
2	Alcohol	15.14	108-93-0	C₆H₁₂O	Cyclohexanol	4.5 ± 1.6	–
3	Alcohol	9.01	116-09-6	C₃H₆O₂	Hydroxyacetone	36.2 ± 20.2	48.8 ± 18.2
4	Aldehydes	2.65	66-25-1	C₆H₁₂O	Hexanal	6.8 ± 3.9	5.1 ± 1.1
5	Fatty acids	25.65	79-09-4	C₃H₆O₂	Propanoic acid	5.7 ± 1.9	8.38 ± 2.0
6	Fatty acids	29.17	591-81-1	C₄H₈O₃	Butanoic acid, 4-hydroxy-	2.3 ± 1.0	4.2 ± 1.5
7	Fatty acids	35.08	503-74-2	C₅H₁₀O₂	Isovaleric acid	16.1 ± 5.3	18.4 ± 4.1
8	Hemiterpenoids	41.79	80-59-1	C₅H₈O₂	Tiglic acid	2.7 ± 1.2	7.5 ± 7.3
9	Ketone	10.86	110-93-0	C₈H₁₄O	6-Methyl-5-hepten-2-one	8.7 ± 3.5	10.7 ± 3.6
10	Monoterpenoids	2.50	79-92-5	C₁₀H₁₆	Camphene	18.5 ± 7.5	–
11	Monoterpenoids	2.94	18172-67-3	C₁₀H₁₆	β-Pinene	2.0 ± 1.2	1.6 ± 0.7
12	Monoterpenoids	3.16	3387-41-5	C₁₀H₁₆	Sabinene	4.8 ± 2.2	5.5 ± 1.2
13	Monoterpenoids	3.35	28634-89-1	C₁₀H₁₆	β-Thujene	2.4 ± 1.1	2.4 ± 0.7
14	Monoterpenoids	4.38	99-86-5	C₁₀H₁₆	α-Terpinene	16.2 ± 8.0	17.9 ± 7.5
15	Monoterpenoids	4.86	5989-27-5	C₁₀H₁₆	d-Limonene	3.5 ± 1.8	4.0 ± 0.4
16	Monoterpenoids	5.01	555-10-2	C₁₀H₁₆	β-Phellandrene	5.6 ± 2.6	6.9 ± 2.9
17	Monoterpenoids	6.36	99-85-4	C₁₀H₁₆	γ-Terpinene	22.6 ± 11.1	24.8 ± 10.0
18	Monoterpenoids	7.31	99-87-6	C₁₀H₁₄	p-Cymene	2.3 ± 1.9	2.7 ± 0.9
19	Monoterpenoids	5.34	470-82-6	C₁₀H₁₈O	Eucalyptol	160.5 ± 53.8	136.8 ± 56.3
20	Monoterpenoids	16.01	4613-37-0	C₁₀H₁₄O	Filifolone	6.9 ± 7.2	10.0 ± 13.4
21	Monoterpenoids	20.42	76-22-2	C₁₀H₁₆O	Camphor	66.1 ± 17.8	62.1 ± 22.5
22	Monoterpenoids	23.70	50764-55-1	C₁₂H₁₈O₂	trans-Chrysanthenyl acetate	384.1 ± 125.5	412.7 ± 181.9
23	Monoterpenoids	24.85	30460-92-5	C₁₀H₁₄O	Pinocarvone	3.1 ± 1.8	1.1 ± 0.3
24	Monoterpenoids	26.85	67999-48-8	C₁₂H₁₈O₂	cis-Chrysanthenyl acetate	52.0 ± 9.3	69.3 ± 15.7
25	Monoterpenoids	27.09	5655-61-8	C₁₂H₂₀O₂	(–)-Bornyl acetate	4.8 ± 3.8	–
26	Monoterpenoids	27.65	78-70-6	C₁₀H₁₈O	Linalool	6.6 ± 1.9	–
27	Monoterpenoids	29.74	562-74-3	C₁₀H₁₈O	Terpinen-4-ol	4.1 ± 1	4.4 ± 1.6
28	Monoterpenoids	32.94	6712-79-4	C₁₀H₁₆O	Isopinocarveol	4.2 ± 1	1.7 ± 0.6
29	Monoterpenoids	33.32	16750-88-2	C₁₁H₁₈O₂	3,6-Octadienoic acid, 3,7-dimethyl-, methyl ester, (Z)-	6.2 ± 5.9	8.1 ± 9.4
30	Monoterpenoids	36.46	98-55-5	C₁₀H₁₈O	α-Terpineol	10.8 ± 4.1	11.2 ± 5.3
31	Monoterpenoids	39.54	55722-60-6	C₁₀H₁₆O	cis-Chrysanthenol	15.9 ± 2.9	20.2 ± 8.0
32	Pyrazines	9.8	123-32-0	C₆H₈N₂	Pyrazine 2,5-dimethyl	7.7 ± 6.3	15.7 ± 2.1
33	Sesquiterpenoids	19.65	17699-14-8	C₁₅H₂₄	α-Cubebene	4.6 ± 2.9	5.4 ± 2.8
34	Sesquiterpenoids	27.19	87-44-5	C₁₅H₂₄	β-Caryophyllene	16.7 ± 10.4	30.9 ± 8.6
35	Sesquiterpenoids	27.92	515-13-9	C₁₅H₂₄	β-Elemene	60.2 ± 25.9	113.8 ± 76.8
36	Sesquiterpenoids	35.27	489-39-4	C₁₅H₂₄	Aromandendrene	7.8 ± 2.8	15.8 ± 9.3
37	Sesquiterpenoids	35.75	473-13-2	C₁₅H₂₄	α-Selinene	5.1 ± 2.3	11.4 ± 6.9
38	Sesquiterpenoids	37.49	495-61-4	C₁₅H₂₄	β-Bisabolene	0.9 ± 0.50	1.1 ± 0.8
39	Sesquiterpenoids	37.96	75023-40-4	C₁₅H₂₄	Helminthogermacrene	3.7 ± 1.9	7.1 ± 5.4
40	Sesquiterpenoids	46.46	1139-30-6	C₁₅H₂₄O	Caryophyllene oxide	2.0 ± 0.6	2.3 ± 1.0
41	Sesquiterpenoids	46.75	–	C₁₅H₂₄O	cis-Z-α-Bisabolene epoxide	5.6 ± 3.0	9.7 ± 5.4

RT retention time

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