Table 1 Effect of fertilizer application on BAs contents (µg·L⁻¹) in 'Royal' grape cultivars depending on soil management and years of research

Putrescine

Olive Blackwater

9.21 ± 0.6b

14.91 ± 0.4 ns

33.42 ± 2.1b

6.72 ± 0.1c

7.92 ± 0.6a

6.83 ± 0.3 ns

13.92 ± 0.7b

12.82 ± 1.2c

39.72 ± 2.9c

Antep Radish

7.15 ± 0.1c

14.83 ± 0.7

50.11 ± 2.1a

7.71 ± 0.2c

8.01 ± 0.2a

7.32 ± 0.4

21.93 ± 0.6a

19.81 ± 1.2b

28.91 ± 9.5c

Broccoli

8.12 ± 0.2c

19.66 ± 1.2

10.43 ± 0.5c

28.61 ± 1.2b

8.62 ± 0.1a

7.31 ± 0.8

20.91 ± 1.7a

12.23 ± 0.4c

89.00 ± 2.1b

Control

11.73 ± 0.2a

19.12 ± 5.1

8.4 ± 0.4c

43.03 ± 0.8a

5.73 ± 0.1b

6.12 ± 0.9

12.3 ± 10.9b

32.82 ± 1.6a

116.83 ± 4.0a

Significance

0.000

0.451

0.000

0.000

0.001

0.583

0.000

0.000

0.000

Cadaverine

Olive Blackwater

1.12 ± 0.1c

3.32 ± 0.5 ns

1.82 ± 0.2b

6.40 ± 0.3a

3.42 ± 0.2b

2.12 ± 0.4b

2.86 ± 0.3b

1.55 ± 0.1b

4.41 ± 0.2a

Antep Radish

1.81 ± 0.1ab

3.33 ± 0.3

3.61 ± 0.1a

3.42 ± 0.1b

2.33 ± 0.1b

6.31 ± 0.2a

2.19 ± 0.1b

5.32 ± 0.5a

1.57 ± 0.1b

Broccoli

1.50 ± 0.2bc

2.38 ± 0.0

2.28 ± 0.2b

2.26 ± 0.1c

6.41 ± 0.6a

2.27 ± 0.1b

5.82 ± 0.5a

1.95 ± 0.1b

1.30 ± 0.1b

Control

2.04 ± 0.0a

2.66 ± 0.2

4.11 ± 0.3a

6.70 ± 0.5a

3.08 ± 0.2b

1.55 ± 0.3b

2.28 ± 0.1b

1.34 ± 0.1b

4.44 ± 0.4a

Significance

0.003

0.145

0.001

0.000

0.000

0.000

0.000

0.000

0.000

Agmatine

Olive Blackwater

2.51 ± 0.2 ns

3.42 ± 0.1b

3.52 ± 0.1b

2.40 ± 0.1b

3.71 ± 0.1 ns

2.83 ± 0.1a

3.19 ± 0.4bc

4.07 ± 0.2 ns

3.18 ± 0.3 ns

Antep Radish

2.91 ± 0.2

3.36 ± 0.3b

5.80 ± 0.3a

3.01 ± 0.2a

3.27 ± 0.2

2.42 ± 0.1b

2.77 ± 0.2c

4.12 ± 0.1

2.65 ± 0.2

Broccoli

2.90 ± 0.1

3.73 ± 0.1b

2.32 ± 0.1b

3.18 ± 0.1a

2.71 ± 0.3

2.62 ± 0.1a

3.70 ± 0.1a

3.85 ± 0.2

3.13 ± 0.2

Control

3.02 ± 0.1

4.35 ± 0.0a

2.27 ± 0.1b

2.83 ± 0.2ab

3.36 ± 0.1

2.42 ± 0.0b

3.52 ± 0.3ab

4.60 ± 0.1

2.73 ± 0.1

Significance

0.281

0.009

0.000

0.024

0.083

0.004

0.009

0.080

0.106

Spermine

Olive Blackwater

0.09 ± 0.0 ns

0.07 ± 0.0 ns

0.10 ± 0.0 ns

0.10 ± 0.0 ns

0.11 ± 0.0 ns

0.11 ± 0.0b

0.13 ± 0.0ab

0.10 ± 0.0c

0.21 ± 0.0c

Antep Radish

0.07 ± 0.0

0.08 ± 0.0

0.12 ± 0.0

0.12 ± 0.0

0.08 ± 0.0

0.10 ± 0.0b

0.11 ± 0.0b

0.07 ± 0.0d

0.40 ± 0.0a

Broccoli

0.08 ± 0.0

0.11 ± 0.0

0.12 ± 0.0

0.12 ± 0.0

0.08 ± 0.0

0.09 ± 0.0b

0.19 ± 0.0a

0.36 ± 0.0a

0.30 ± 0.0b

Control

0.10 ± 0.0

0.08 ± 0.0

0.11 ± 0.0

0.15 ± 0.0

0.10 ± 0.0

0.19 ± 0.0a

0.15 ± 0.0ab

0.28 ± 0.0b

0.23 ± 0.0c

Significance

0.217

0.239

0.677

0.309

0.259

0.006

0.043

0.000

0.000

Spermidine

Olive Blackwater

0.15 ± 0.0b

0.20 ± 0.1bc

0.24 ± 0.0 ns

0.25 ± 0.0b

0.74 ± 0.0 ns

0.79 ± 0.0 ns

0.03 ± 0.0 ns

0.05 ± 0.1 ns

0.05 ± 0.0c

Antep Radish

0.19 ± 0.0b

0.24 ± 0.1a

0.26 ± 0.0

0.30 ± 0.0b

0.87 ± 0.0

0.94 ± 0.1

0.03 ± 0.0

0.04 ± 0.0

0.08 ± 0.0bc

Broccoli

0.25 ± 0.0a

0.15 ± 0.0c

0.27 ± 0.0

0.30 ± 0.0b

0.97 ± 0.0

0.90 ± 0.0

0.03 ± 0.0

0.05 ± 0.1

0.16 ± 0.0ab

Control

0.18 ± 0.1b

0.22 ± 0.1a

0.24 ± 0.0

0.68 ± 0.0a

0.90 ± 0.0

0.92 ± 0.0

0.04 ± 0.1

0.05 ± 0.0

0.23 ± 0.0a

Significance

0.009

0.022

0.139

0.012

0.291

0.348

0.590

0.546

0.006

Histamine

Olive Blackwater

6.07 ± 0.4b

10.45 ± 0.7 ns

9.39 ± 0.0b

18.03 ± 0.9a

13.78 ± 1.1b

9.05 ± 0.7b

10.59 ± 0.8b

6.63 ± 1.1b

12.42 ± 0.3a

Antep Radish

8.18 ± 0.4a

11.00 ± 0.5

12.19 ± 0.3a

13.70 ± 0.5b

10.55 ± 0.5c

17.66 ± 0.5a

8.04 ± 0.3c

14.23 ± 0.2a

6.29 ± 0.6b

Broccoli

6.73 ± 0.4b

10.46 ± 0.5

10.23 ± 0.4b

8.93 ± 0.4c

18.52 ± 0.9a

9.07 ± 0.4b

15.41 ± 0.6a

6.97 ± 0.7b

5.13 ± 0.2b

Control

9.34 ± 0.2a

12.21 ± 0.7

13.15 ± 0.5a

19.87 ± 0.8a

11.91 ± 1.1bc

6.12 ± 0.3c

8.64 ± 0.7bc

5.30 ± 0.3b

13.18 ± 0.2a

Significance

0.001

0.204

0.000

0.000

0.001

0.000

0.000

0.000

0.000

Tryptamine

Olive Blackwater

0.30 ± 0.0c

4.61 ± 0.3c

6.65 ± 0.5bc

10.78 ± 0.3b

10.8 ± 0.3b

8.37 ± 0.6a

9.24 ± 0.7bc

7.84 ± 0.6c

14.89 ± 0.4b

Antep Radish

4.26 ± 0.1a

5.57 ± 0.2b

7.98 ± 0.2a

7.53 ± 0.4c

7.75 ± 0.4b

3.32 ± 0.1b

7.26 ± 0.6c

23.14 ± 0.9a

6.94 ± 0.3c

Broccoli

3.65 ± 0.1b

4.92 ± 0.3bc

6.16 ± 0.4c

5.52 ± 0.4d

15.67 ± 0.4a

1.58 ± 0.1c

19.41 ± 0.7a

10.78 ± 0.8b

6.36 ± 0.4c

Control

4.05 ± 0.1a

7.26 ± 0.4a

7.39 ± 0.2ab

13.96 ± 0.4a

9.80 ± 0.4b

1.24 ± 0.1c

9.98 ± 0.7b

8.47 ± 0.6bc

19.28 ± 0.6a

Significance

0.000

0.001

0.027

0.000

0.000

0.000

0.000

0.000

0.000

Serotonin

Olive Blackwater

1.25 ± 0.1 ns

1.10 ± 0.2 ns

0.88 ± 0.2a

0.54 ± 0.0 ns

0.55 ± 0.0 ns

0.59 ± 0.0b

0.58 ± 0.0c

0.51 ± 0.0b

0.40 ± 0.0c

Antep Radish

1.00 ± 0.0

1.17 ± 0.1

0.46 ± 0.0b

0.55 ± 0.0

0.45 ± 0.0

0.50 ± 0.0c

0.53 ± 0.0c

0.40 ± 0.0c

0.65 ± 0.1a

Broccoli

1.07 ± 0.2

1.48 ± 0.0

0.49 ± 0.0b

0.59 ± 0.0

0.40 ± 0.1

0.43 ± 0.0c

0.85 ± 0.0a

0.60 ± 0.0a

0.53 ± 0.0b

Control

1.36 ± 0.1

1.19 ± 0.0

0.51 ± 0.0b

0.60 ± 0.0

0.48 ± 0.0

0.98 ± 0.0a

0.72 ± 0.0b

0.49 ± 0.0b

0.44 ± 0.0c

Significance

0.172

0.186

0.015

0.167

0.224

0.000

0.001

0.003

0.000

Trimethylamine

Olive Blackwater

0.62 ± 0.1 ns

0.65 ± 0.0a

0.86 ± 0.2 ns

1.87 ± 0.4 ns

1.44 ± 0.0b

2.25 ± 0.6 ns

2.69 ± 0.2 ns

2.95 ± 1.2a

0.69 ± 0.0 ns

Antep Radish

0.61 ± 0.1

0.61 ± 0.0ab

1.24 ± 0.1

1.06 ± 0.0

1.37 ± 0.0b

2.52 ± 0.1

3.29 ± 0.2

0.65 ± 0.0b

0.71 ± 0.0

Broccoli

0.78 ± 0.0

0.54 ± 0.0b

1.14 ± 0.2

0.94 ± 0.0

1.34 ± 0.0b

2.80 ± 0.2

3.13 ± 0.1

0.61 ± 0.0b

0.76 ± 0.0

Control

0.68 ± 0.0

0.51 ± 0.0b

1.53 ± 0.1

1.15 ± 0.2

2.1 ± 0.2a

3.26 ± 0.3

3.28 ± 0.2

0.56 ± 0.1b

0.80 ± 0.0

Significance

0.261

0.053

0.118

0.055

0.004

0.265

0.080

0.050

0.112

Dopamine

Olive Blackwater

0.76 ± 0.0c

1.0 ± 0.0b

0.79 ± 0.0bc

0.66 ± 0.0c

0.65 ± 0.0b

1.09 ± 0.0a

0.38 ± 0.0b

0.85 ± 0.0a

0.32 ± 0.0b

Antep Radish

1.05 ± 0.0b

0.67 ± 0c

1.31 ± 0.0a

0.46 ± 0.0d

1.16 ± 0.0a

0.55 ± 0.0c

0.94 ± 0.0a

0.34 ± 0.0b

0.24 ± 0.0c

Broccoli

1.16 ± 0.1ab

1.41 ± 0a

0.87 ± 0.1b

1.63 ± 0.0a

0.67 ± 0.0b

0.43 ± 0.0d

0.4 ± 0.0b

0.28 ± 0.0b

1.01 ± 0.0a

Control

1.28 ± 0.0a

1.0 ± 0.1b

0.68 ± 0.0c

0.83 ± 0.1b

0.53 ± 0.0c

0.88 ± 0.0b

0.34 ± 0.0b

0.87 ± 0.0a

0.25 ± 0.0c

Significance

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

0.000

Norepinephrine

Olive Blackwater

0.31 ± 0.0b

0.4 ± 0.0 ns

0.59 ± 0.0 ns

2.08 ± 0.2 ns

2.9 ± 0.6 ns

10.23 ± 4.2 ns

9.08 ± 1.0b

12 ± 5.9a

0.17 ± 0.0 ns

Antep Radish

0.32 ± 0.0b

0.5 ± 0.1

1.31 ± 0.8

2.87 ± 0.2

2.9 ± 0.4

10.48 ± 2.1

13.51 ± 2.6a

0.2 ± 0.0b

0.22 ± 0.0

Broccoli

0.34 ± 0.0ab

0.5 ± 0.0

2.46 ± 0.6

2.23 ± 0.4

3.0 ± 0.2

9.64 ± 0.8

13.37 ± 1.8a

0.2 ± 0.0b

0.22 ± 0.0

Control

0.38 ± 0.0a

0.6 ± 0.0

2.21 ± 0.9

1.96 ± 0.2

4.4 ± 0.5

13.3 ± 0.9

13.76 ± 0.8a

0.2 ± 0.0b

0.19 ± 0.0

Significance

0.054

0.293

0.267

0.164

0.112

0.726

0.038

0.053

0.477