Table 3 The amino acid contents (µg/l) of harvested ‘Karaerik’ grape berries for various individual and combined EO treatments aimed at countering B. Cinerea

C

290.25 ± 41.75c

124.93 ± 36.56b

258.83 ± 33.72bc

353.47 ± 24.95b

162.58 ± 34.88ab

85.26 ± 21.38b

211.23 ± 16.09bcd

222.38 ± 22.90ab

259.68 ± 36.30b

121.31 ± 55.27ab

352.25 ± 33.01 cd

F

306.75 ± 33.50bc

128.13 ± 36.01b

238.16 ± 36.67c

343.18 ± 40.00b

143.72 ± 19.89ab

115.52 ± 26.20ab

216.71 ± 11.77bcd

220.03 ± 23.55ab

251.52 ± 22.67b

101.61 ± 58.00b

349.47 ± 37.00 cd

O

429.12 ± 53.45bc

208.58 ± 31.08ab

341.35 ± 45.75abc

394.96 ± 35.87b

136.41 ± 55.90ab

118.43 ± 33.67ab

167.29 ± 16.00d

222.58 ± 10.77ab

276.97 ± 38.00b

95.69 ± 40.27b

355.80 ± 40.05 cd

OF

448.64 ± 47.30bc

242.48 ± 65.12ab

404.41 ± 57.60ab

422.50 ± 60.71b

148.40 ± 16.36ab

193.66 ± 45.77a

261.34 ± 11.10abc

223.24 ± 23.78ab

358.23 ± 60.56ab

285.84 ± 60.21ab

529.82 ± 45.90abc

OS

686.41 ± 37.21a

234.09 ± 23.00ab

321.20 ± 12.56abc

414.11 ± 27.62b

127.23 ± 33.67b

143.57 ± 21.36ab

219.26 ± 15.68bcd

207.00 ± 40.00ab

297.12 ± 44.87ab

130.70 ± 70.99ab

536.69 ± 20.00abc

OSF

418.55 ± 55.76bc

261.69 ± 30.08ab

435.67 ± 52.79a

499.48 ± 50.79ab

144.87 ± 40.89ab

154.75 ± 15.88ab

221.12 ± 20.00abcd

275.81 ± 28.89ab

361.20 ± 36.80ab

120.50 ± 67.24ab

473.75 ± 67.05abcd

S

441.79 ± 43.70bc

217.90 ± 56.51ab

338.89 ± 60.71abc

390.09 ± 57.90b

140.00 ± 60.43ab

124.21 ± 55.30ab

179.13 ± 55.09 cd

216.64 ± 35.76ab

288.87 ± 60.35ab

93.37 ± 56.26b

354.42 ± 33.90 cd

SF

447.96 ± 41.69bc

321.27 ± 22.67a

411.98 ± 48.60ab

608.84 ± 10.18a

139.26 ± 35.09ab

198.35 ± 45.14a

309.99 ± 34.55a

291.80 ± 21.00a

312.53 ± 11.20ab

164.23 ± 50.20ab

632.04 ± 30.06a

T

291.24 ± 55.76c

174.96 ± 39.12ab

311.32 ± 41.77abc

405.17 ± 40.79b

137.54 ± 16.55ab

128.78 ± 25.37ab

211.52 ± 11.80bcd

240.29 ± 26.90ab

290.62 ± 31.09b

116.49 ± 77.20ab

395.83 ± 37.03bcd

TF

433.85 ± 23.67bc

242.08 ± 65.06ab

382.88 ± 25.67abc

447.41 ± 59.01ab

153.85 ± 40.81ab

133.23 ± 50.67ab

187.74 ± 13.01bcd

252.54 ± 29.85ab

311.80 ± 38.00ab

108.54 ± 70.29ab

402.67 ± 66.00bcd

TO

528.22 ± 59.72ab

248.11 ± 55.16ab

400.68 ± 63.55ab

486.75 ± 79.99ab

156.52 ± 18.37ab

207.72 ± 22.50a

258.16 ± 18.03abc

271.33 ± 27.00ab

329.97 ± 34.80ab

147.46 ± 60.89ab

557.86 ± 36.05ab

TOF

327.61 ± 63.98bc

268.37 ± 33.67ab

351.31 ± 32.75abc

373.10 ± 69.20b

155.70 ± 20.01ab

172.56 ± 33.70ab

174.06 ± 11.50 cd

178.60 ± 11.78b

397.87 ± 47.34a

394.87 ± 23.26ab

309.23 ± 40.08d

TOS

520.65 ± 30.45ab

251.94 ± 29.58ab

318.86 ± 40.45abc

431.61 ± 33.67ab

164.28 ± 33.04ab

163.34 ± 25.30ab

236.39 ± 15.47abcd

197.99 ± 13.60ab

359.73 ± 80.67ab

258.31 ± 66.00ab

466.73 ± 39.67abcd

TOSF

477.18 ± 67.74abc

225.26 ± 29.98ab

380.95 ± 65.62abc

438.41 ± 65.09ab

153.19 ± 27.05ab

134.06 ± 20.38ab

191.05 ± 22.00bcd

247.50 ± 23.66ab

309.65 ± 26.07ab

106.40 ± 13.20ab

395.65 ± 23.00bcd

TS

505.41 ± 41.34abc

208.39 ± 38.10ab

332.67 ± 50.79abc

425.38 ± 40.96b

178.07 ± 47.57a

177.26 ± 24.36ab

268.78 ± 11.05ab

248.53 ± 67.89ab

261.01 ± 89.02b

137.27 ± 66.90ab

487.34 ± 38.06abcd

TSF

465.05 ± 63.50abc

247.99 ± 25.60ab

423.37 ± 28.40a

390.22 ± 66.70b

174.02 ± 50.51b

208.97 ± 27.36a

244.22 ± 18.00abcd

187.62 ± 68.09ab

377.34 ± 60.36ab

411.31 ± 56.20a

464.01 ± 37.09abcd

Significance

2.74e-05 ***

0.0078 **

0.0016 **

0.0018 **

0.0001***

0.0024 **

4.06e-05 ***

0.0224 *

0.00621 **

0.00259 **

1.57e-05 ***

C

122.23 ± 16.15de

149.63 ± 26.90b

149.57 ± 24.16b

278.21 ± 44.01de

440.30 ± 53.47d

160.88 ± 45.77ab

80.17 ± 33.76c

178.48 ± 87.10d

153.18 ± 10.77bc

223.51 ± 11.57c

F

109.74 ± 19.11e

145.18 ± 21.99b

145.55 ± 88.90b

273.79 ± 55.67de

428.29 ± 35.67d

138.54 ± 41.00b

76.41 ± 36.76c

174.96 ± 70.77d

147.10 ± 16.88c

213.68 ± 56.10c

O

129.04 ± 16.00cde

207.88 ± 28.77ab

146.42 ± 90.00b

291.22 ± 23.43cde

605.86 ± 55.23abcd

107.04 ± 55.67b

138.84 ± 37.70bc

174.54 ± 78.15d

128.45 ± 11.10d

214.03 ± 77.67c

OF

232.87 ± 20.15ab

256.27 ± 26.90ab

195.67 ± 26.11ab

422.95 ± 59.27abcd

812.09 ± 46.56abc

225.60 ± 66.00ab

277.83 ± 32.03ab

433.34 ± 09.00b

196.39 ± 20.09a

269.97 ± 69.90b

OS

172.77 ± 35.55abcde

212.42 ± 90.00ab

177.36 ± 60.56ab

414.81 ± 42.09abcd

753.51 ± 57.66abcd

115.40 ± 49.76b

131.02 ± 55.53bc

235.94 ± 12.16 cd

120.39 ± 35.06d

212.53 ± 33.80c

OSF

164.50 ± 82.10abcde

232.38 ± 88.05ab

195.54 ± 11.88ab

376.11 ± 32.98bcd

731.77 ± 89.56abcd

133.12 ± 96.70b

155.14 ± 70.13abc

223.61 ± 60.55 cd

93.37 ± 55.60e

281.73 ± 43.57b

S

127.45 ± 78.16cde

204.24 ± 26.97ab

154.20 ± 36.19b

300.08 ± 43.78cde

600.78 ± 44.32abcd

103.86 ± 80.00b

131.93 ± 22.89bc

182.50 ± 05.80d

125.33 ± 37.44d

223.23 ± 70.09c

SF

254.62 ± 17.55a

290.29 ± 28.99a

224.95 ± 55.07a

561.58 ± 83.54a

899.48 ± 34.56a

144.83 ± 65.87ab

220.38 ± 60.09abc

320.54 ± 56.16c

195.41 ± 22.06a

283.58 ± 87.15b

T

134.64 ± 17.16cde

185.00 ± 20.90ab

165.37 ± 43.23ab

309.85 ± 66.43cde

535.11 ± 45.57bcd

151.90 ± 23.65ab

112.46 ± 33.77bc

194.20 ± 87.16d

155.86 ± 18.06bc

237.31 ± 89.68c

TF

146.18 ± 22.10bcde

235.62 ± 11.91ab

164.64 ± 35.39ab

328.30 ± 25.52bcde

686.01 ± 87.98abcd

121.50 ± 30.70b

157.93 ± 89.00abc

196.44 ± 66.10d

145.70 ± 42.70c

240.95 ± 55.07c

TO

218.31 ± 67.00abc

293.47 ± 40.90a

201.09 ± 34.28a

491.19 ± 17.43ab

842.10 ± 56.67ab

159.58 ± 86.09ab

199.68 ± 37.76abc

274.09 ± 56.78c

155.27 ± 89.15bc

266.59 ± 50.15bc

TOF

187.58 ± 23.15abcde

259.82 ± 25.09ab

222.69 ± 65.56a

187.90 ± 75.43e

499.24 ± 87.23 cd

388.82 ± 70.60a

324.73 ± 11.00a

595.52 ± 58.10a

219.09 ± 17.34a

335.22 ± 36.67ab

TOS

205.17 ± 89.10abcd

237.05 ± 55.97ab

210.22 ± 43.54a

362.36 ± 13.23bcde

692.43 ± 45.64abcd

241.48 ± 46.94ab

232.61 ± 36.78abc

452.34 ± 70.88b

173.54 ± 58.22b

261.59 ± 16.34bc

TOSF

144.79 ± 60.55bcde

203.72 ± 09.04ab

164.57 ± 92.25ab

323.83 ± 43.55bcde

677.95 ± 55.54abcd

119.03 ± 50.66b

136.06 ± 55.80bc

194.09 ± 13.87d

142.83 ± 45.33c

242.28 ± 78.26c

TS

175.30 ± 19.10abcde

208.33 ± 56.89ab

201.79 ± 33.98a

468.75 ± 65.89abc

683.95 ± 32.43abcd

101.27 ± 43.78b

148.68 ± 12.79bc

211.40 ± 60.12d

143.30 ± 65.70c

288.72 ± 60.05b

TSF

206.52 ± 11.16abcd

259.57 ± 77.70ab

246.94 ± 43.54a

322.20 ± 55.78bcde

711.81 ± 46.55abcd

342.72 ± 56.78ab

280.06 ± 30.09ab

528.43 ± 77.17a

188.00 ± 50.78a

369.31 ± 50.45a

Significance

1.8e-05 ***

0.0046 **

0.0004 ***

6.61e-07 ***

0.0001 ***

0.0019 **

6.42e-05 ***

2.7e-05 ***

0.0344 *

0.0002***