Table 2 Compounds identified by GC–MS of the essential oils of Tripleurospermum disciforme (C.A.Mey.) Sch.Bip., Tanacetum parthenium (L.) Sch.Bip. and Achillea biebersteinii Afan

1

1,3-Cyclopentadiene, 5-(1,1-dimethylethyl)-

1.72 ± 0.00^a

C₉H₁₄

2

1-Butanol, 2-methyl-

0.13 ± 0.02^a

C₅H₁₂O

3

Isobutyric acid, isobutyl ester

0.07 ± 0.01^a

C₈H₁₆O₂

4

Tricyclene

0.57 ± 0.02^a

C₁₀H₁₆

5

α-Thujene

0.40 ± 0.00^a

C₁₀H₁₆

6

α-Pinene

0.48 ± 0.02^b

1.03 ± 0.02^a

C₁₀H₁₆

7

Camphene

9.40 ± 0.04^a

0.19 ± 0.00^b

C₁₀H₁₆

8

Sabinene

0.12 ± 0.01^b

2.17 ± 0.01^a

C₁₀H₁₆

9

β-Pinene

0.33 ± 0.00^a

C₁₀H₁₆

10

β-Myrcene

1.31 ± 0.00^a

C₁₀H₁₆

11

Furan, 2-pentyl-

0.20 ± 0.00^a

0.19 ± 0.01^a

C₉H₁₄O

12

α-Phellandrene

1.39 ± 0.01^a

C₁₀H₁₆

13

δ-Carene

0.22 ± 0.02^b

1.32 ± 0.01^a

C₁₀H₁₆

14

p-Cymene

3.27 ± 0.00^b

15.31 ± 0.03^a

C₁₀H₁₄

15

β-Ocimene

0.96 ± 0.01^a

C₁₀H₁₆

16

γ-Terpinene

1.36 ± 0.01^b

2.54 ± 0.00^a

C₁₀H₁₆

17

Filifolone

0.27 ± 0.02^a

C₁₀H₁₄O

18

α-Terpinolene

1.15 ± 0.00^a

C₁₀H₁₆

19

Linalool oxide

0.39 ± 0.00^a

C₁₀H₁₈O₂

20

Linalool

34.49 ± 0.02^a

C₁₀H₁₈O

21

2H-Pyran-3(4H)-one, 6-ethenyldihydro-2,2,6-trimethyl-

0.99 ± 0.05^a

C₁₀H₁₆O₂

22

Chrysanthenone

0.47 ± 0.01^a

C₁₀H₁₄O

23

Camphor

0.15 ± 0.01^b

43.43 ± 0.03^a

C₁₀H₁₆O

24

(+)-Camphor

0.38 ± 0.01^a

C₁₀H₁₆O

25

Borneol

0.95 ± 0.01^a

C₁₀H₁₈O

26

Albene

0.13 ± 0.00^a

C₁₂H₁₈

27

Lilac aldehyde D

0.15 ± 0.00^a

C₁₀H₁₆O₂

28

Nerol oxide

0.83 ± 0.00^a

C₁₀H₁₆O

30

β-Citronellene

0.14 ± 0.01^a

C₁₀H₁₈

31

Biisobutenyl

0.28 ± 0.00^a

C₈H₁₄

32

(-)-Terpinen-4-ol

1.38 ± 0.04^a

C₁₀H₁₈O

33

Terpinen-4-ol

5.04 ± 0.02^a

C₁₀H₁₈O

34

α-Terpineol

7.43 ± 0.01^a

C₁₀H₁₈O

35

Cyclofenchene

0.45 ± 0.03^a

C₁₀H₁₆

36

Sabinol

0.33 ± 0.00^a

C₁₀H₁₆O

37

Captan

0.70 ± 0.00^a

C₉H₈Cl₃NO₂S

38

cis-Geraniol

0.75 ± 0.00^a

C₁₀H₁₈O

39

Linalool acetate

4.35 ± 0.02^a

C₁₂H₂₀O₂

40

Geraniol

2.70 ± 0.00^a

C₁₀H₁₈O

41

Bornyl acetate

6.76 ± 0.03^a

C₁₂H₂₀O₂

42

(-)-Bornyl acetate

0.39 ± 0.01^a

C₁₂H₂₀O₂

43

Silphiperfol-5-ene

0.16 ± 0.01^a

C₁₅H₂₄

44

α-Guaiene

0.90 ± 0.00^a

C₁₅H₂₄

45

α-Terpineol acetate

1.22 ± 0.03^a

C₁₂H₂₀O₂

46

Nerol acetate

1.05 ± 0.00^a

C₁₂H₂₀O₂

47

γ-Patchoulene

0.15 ± 0.00^a

C₁₅H₂₄

48

α-Cubebene

0.56 ± 0.01^a

C₁₅H₂₄

49

Geraniol acetate

2.15 ± 0.02^a

C₁₂H₂₀O₂

50

Modephene

10.00 ± 0.01^a

0.37 ± 0.02^b

C₁₅H₂₄

51

cis-Jasmone

1.35 ± 0.01^a

C₁₁H₁₆O

52

Caryophyllene

1.66 ± 0.00^a

0.25 ± 0.01^c

0.46 ± 0.02^b

C₁₅H₂₄

53

Propanoic acid, 2-methyl-, 1,7,7-trimethylbicyclo[2.2.1]hept-2-yl ester, exo-

0.49 ± 0.00^a

C₁₄H₂₄O₂

54

Selina-5,11-diene

0.79 ± 0.01^a

C₁₅H₂₄

55

trans-β-Farnesene

0.10 ± 0.00^a

C₁₅H₂₄

56

cis-β-Farnesene

11.94 ± 0.01^a

1.29 ± 0.03^a

C₁₅H₂₄

57

γ-Selinene

0.16 ± 0.02^a

C₁₅H₂₄

58

Germacrene D

2.43 ± 0.03^a

0.22 ± 0.01^b

C₁₅H₂₄

59

Bornyl isovalerate

2.81 ± 0.01^a

C₁₅H₂₆O₂

60

α-Amorphene

1.17 ± 0.04^a

C₁₅H₂₄

61

Aromandendrene

0.05 ± 0.00^a

C₁₅H₂₄

62

β-Bisabolene

0.70 ± 0.01^a

C₁₅H₂₄

63

β-Sesquiphellandrene

6.58 ± 0.02^a

0.64 ± 0.00^b

C₁₅H₂₄

64

3H-Pyrazol-3-one, 2,4-dihydro-2-methyl-5-phenyl-

0.17 ± 0.00^a

C₁₀H₁₀N₂O

65

Anisole, p-1-cyclohexen-1-yl-

55.95 ± 0.03^a

4.99 ± 0.01^b

C₁₃H₁₆O

66

trans-Nerolidol

0.10 ± 0.01^a

C₁₅H₂₆O

67

Bornyl tiglate

0.44 ± 0.00^a

C₁₅H₂₄O₂

68

Spathulenol

1.52 ± 0.01^a

C₁₅H₂₄O

69

Dendrasaline

1.14 ± 0.03^a

C₁₅H₂₂O

70

Benzoic acid, hexyl ester

0.09 ± 0.00^a

C₁₃H₁₈O₂

71

Caryophyllene oxide

0.65 ± 0.00^a

C₁₅H₂₄O

72

Mintketone=Salvial-4(14)-en-1-one

1.05 ± 0.01^a

C₁₅H₂₄O

73

9-Oxatetracyclo[5.4.0.0(3,10).0(4,8)]undeca-5-en-2-one

0.83 ± 0.01^a

C₁₀H₁₀O₂

74

δ-Cadinene

0.51 ± 0.03^a

C₁₅H₂₄

75

2-methyl-2-vinyl-5-isopropyltetrahydrofuran

0.20 ± 0.00^a

C₁₀H₁₈O

76

cis-Farnesol

2.79 ± 0.00^a

C₁₅H₂₆O

77

γ-Eudesmol

0.37 ± 0.00^b

0.47 ± 0.02^a

C₁₅H₂₆O

78

Valencene

0.83 ± 0.00^a

C₁₅H₂₄

79

Methyl jasmonate

0.47 ± 0.01^a

C₁₃H₂₀O₃

80

τ-Cadinol

0.81 ± 0.00^a

C₁₅H₂₆O

81

6-Hydroxy caryophyllene

0.42 ± 0.01^a

C₁₅H₂₄O

82

Neointermedeol

1.75 ± 0.03^a

C₁₅H₂₆O

83

β-Eudesmol

1.18 ± 0.01^a

C₁₅H₂₆O

84

2-Norcaranone, 3-methyl-

0.54 ± 0.00^a

C₈H₁₂O

85

α-Bisabolol

0.52 ± 0.01^a

C₁₅H₂₆O

86

4-(1,5-Dimethylhex-4-enyl)cyclohex-2-enone

1.54 ± 0.01^a

C₁₄H₂₂O

87

(1R,7S,E)-7-Isopropyl-4,10-dimethylenecyclodec-5-enol

0.55 ± 0.03^a

C₁₅H₂₄O

88

γ-Costol

0.08 ± 0.02^a

C₁₅H₂₄O

89

Caparratriene

0.57 ± 0.02^a

C₁₅H₂₆

90

15-nor-Prezizaan-7-one

0.34 ± 0.04^a

C₁₄H₂₂O

91

Ascabiol

0.16 ± 0.00^a

C₁₄H₁₂O₂

92

(4R,5S)-4-Methyl-5-phenyl-2-oxazolidinone

0.83 ± 0.03^a

C₁₀H₁₁NO₂

93

Farnesol

0.28 ± 0.02^a

C₁₅H₂₆O

94

(Z)-8-decen-4,6-diyn-1-yl 3-methylbutanoate

0.73 ± 0.01^a

C₁₅H₂₀O₂

95

Phthalic acid, diisobutyl ester

0.16 ± 0.05^a

C₁₆H₂₂O₄

96

(Z)-Tonghaosu

1.18 ± 0.00^a

C₁₃H₁₂O₂

97

Gerany-p-cymene

0.29 ± 0.01^a

C₂₀H₃₀

98

9-Octadecenal, (Z)-

0.19 ± 0.00^a

C₁₈H₃₄O

99

(E)-Tibetin spiroether

0.22 ± 0.00^a

C₁₄H₁₄O₂

100

Hexadecanoic acid

0.75 ± 0.02^a

0.63 ± 0.02^b

C₁₆H₃₂O₂

101

cis-1-Chloro-9-octadecene

0.11 ± 0.03^a

C₁₈H₃₅Cl

102

1,15-Hexadecadiene

0.71 ± 0.00^a

C₁₆H₃₀

104

Behenic alcohol

0.26 ± 0.01^a

C₂₂H₄₆O

105

Z-9-Octadecen-1-ol acetate

0.49 ± 0.01^a

C₂₀H₃₈O₂

106

Octadecane

0.08 ± 0.03^a

C₁₈H₃₈

107

Tricosane

0.54 ± 0.01^a

C₂₃H₄₈

108

Linoleic acid

0.53 ± 0.02^a

C₁₈H₃₂O₂

109

Phytan

0.38 ± 0.01^a

C₂₀H₄₂

Total

98.78

99.55

99.94

Monoterpenes hydrocarbons

0.00

16.2

27.91

Oxygenated monoterpenes

0.15

47.21

51.76

Sesquiterpenes hydrocarbons

34.03

7.15

0.99

Oxygenated sesquiterpenes

2.65

8.03

3

Others

61.95

20.96

16.28