Table 3 Compounds identified from T. harzianum M10 crude extract by GC and LC–MS analysis
Compound | Rt (min) | RI |
|---|---|---|
GC–MS | ||
 2,3-Butanediol, 2TMS derivative | 5.469 | 1054.3 |
 2-Hydroxy-3-methylbutyric acid, 2TMS derivative | 7.158 | 1175.1 |
 2-Hydroxyisocaproic acid, 2TMS derivative | 8.133 | 1244.0 |
 Hexanoic acid, 2TMS derivative | 8.186 | 1247.7 |
 Glycerol, 3TMS derivative | 8.699 | 1283.7 |
 Nicotinic acid, TMS derivative | 8.874 | 1296.1 |
 1,2,3-Butanetriol, 3TMS derivative | 9.000 | 1305.3 |
 Pentanedioic acid, 2TMS derivative | 10.349 | 1407.9 |
 Furandimethanol, 2TMS derivative | 10.532 | 1422.8 |
 3-Hydroxy-2,3-dihydromaltol, 2TMS derivative | 10.997 | 1461.1 |
 DL-Pyroglutamic acid, 2TMS derivative | 11.775 | 1535.8 |
 5-Hydroxy-2-(hydroxymethyl)pyridine, 2TMS derivative | 11.873 | 1545.6 |
 3-Phenyllactic acid, 2TMS derivative | 12.332 | 1598.1 |
 4-Hydroxybenzoic acid, 2TMS derivative | 12.588 | 1636.1 |
 Cyclo(glycylprolyl), TMS derivative | 13.249 | 1743.2 |
 Protocatechuic acid, 3TMS derivative | 13.713 | 1833.5 |
 Homoprotocatechuic acid, 3TMS derivative) | 13.772 | 1846.4 |
 Stearic acid, TMS derivative | 15.300 | 2238.8 |
 Uridine, 4TMS derivative | 16.313 | 2476.5 |
Compound | Monoisotopic mass (Da) | Molecular formula |
|---|---|---|
LC–MS | ||
 2-Aminophenylacetic acid | 151.0636 | C8H9NO2 |
 Nicotinic acid | 123.0325 | C6H5NO2 |
 Benzeneacetaldehyde | 120.0579 | C8H8O |
 Indoleacetic acid | 205.0861 | C12H13O3 |
 7-Hydroxy-3-(2,3-dihydroxybutyl)-1(3H)-isobenzofuranone | 238.0828 | C12H14O5 |
 Tryptophol | 161.0843 | C10H11NO |
 Isoharzianic acid | 365.1844 | C19H27NO6 |
 5-hydroxy-2,3-dimethyl-7-methoxychromone | 220.0758 | C12H12O4 |
 Harzianic acid | 365.1852 | C19H27NO6 |
 Homoharzianic acid | 379.2003 | C20H29NO6 |